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Introductory Notions

Topics:
Units & Standards

Scientific Notation

Significant Digits

Precision

Accuracy

1. Units and Standards

There are 4 fundamental scientific measurements: Mass, Length, Time, and Electric Charge

The following table summarizes their basic SI (International Metric System) units 

Fundamental Quantity Mass Length, distance,
displacement
Time Charge
SI Unit kg (kilogram) m (metre) s (second) C (coulomb)
Symbol m  Δd t Q

2. Scalar vs. Vector

Scalar quantities express only a quantity and a unit

Vector quantities express a quantity, a unit and a direction

Examples:

Quantity Symbol Type Example
 distance Δd scalar  Δd = 10 m
displacement vector = 10 m [E]

 

3. Scientific notation
-very large or very small numbers are difficult to work with when written in common decimal notation
-it is possible to change the SI prefix so the number falls between 0.1 and 1000
-for example 237 000 000 mm can be expressed as 237 km or 0.000 000 895 kg can be expressed as 0.895 mg
-for situations where this is not possible the best method of dealing with this it the use of scientific notation
-scientific notation expresses a number between 1 and 10 x 10 n where n represents the number of places
 the decimal was moved from the right or left
-for example 124 500 000 km   = 1.245 x 108 km

This value 1.245 x 108 really represents 1.245 x 10 x 10 x 10 x 10 x 10 x 10 x 10 x 10
1. To multiple numbers in scientific notation, multiply the coefficients and add the exponents
example  (4.73 x 105 m) (5.82 x 107) = 27.5 x 1012 m2 = 2.75 x 1013 m2  to divide two numbers in scientific notation, subtract the exponents algebraically
example   (1.842 x 106g) ÷ 1.0787 x 102g/mol) = 1.707611 x 104 mol = 1.708 x 104 mol

2.    to add or subtract numbers in scientific notation, convert the numbers so they have the same exponent as
the number with the greatest power of ten. Once this is done add or subtract the coefficients but leave the
exponent alone.

Example:
(3.42 x 106 m) + (8.53 x 103 m) = (3.42 x 106 m) + (0.00853 x 106 m) = 3.42853 x 106 m
= 3.43 x 106 m

Exercise:
1.    Convert each value into scientific notation

a)    0.000 934

b)    7 983 000 000

c)    0.000 000 000 820 57

d)    496 x 106

e)    0.000 06 x 101

f)      309 72 x 10–8


2.    Add, subtract, multiply, or divide the following problems. Express answer in scientific notation
to the correct certainty.

a)    (3.21 x 10–3 + (9.21 x 102)

b)    (8.1 x 103) + (9.21 x 102)

c)    (1.010 1 x 101) – (4.823 x 10–2)

d)    (1.209 x 106) x (8.4 x 107)

e)    (4.89 x 10–4) ÷ (3.20 x 10–2)

Significant digits

1. All non-zero numbers are significant

2. All zeros that are located between two non-zero numbers are significant.

3.    Zeros that are located to the left of a measurement are not significant

4.    Zeros to the right of a measurement may or may not be significant.

 Rules for reporting significant digits in calculations

1.    Multiplying and dividing:
The value with the fewest number of significant digits, going into the calculation,
determines the number of significant digits in your answer.

77.8 km/h x 5.9015 h = 459.136 7 km = 459 km the answer must have 3
significant digits to express the same certainty as the value, 77.8 km/h,
 with the fewest significant digits in the question.

2.    Adding and subtracting:
The value with the fewest number of decimal places, going into the calculation,
determines the number of decimal places that you should report in your answer.

12.5 g + 145.67 g + 70.5456 g + 3.001 g = 231.7166 g = 231.7 g

3.    Rounding Off
To get the appropriate number of significant digits for answers from calculations you do, it is necessary to round off your answers.

-    If your answer ends in a number that is greater than 5 increase the preceding digit by 1.

      2.346 rounded to 3 significant digits is 2.35

-    If your answer ends in a number that is less than 5 leave the preceding number unchanged.

      2.343 rounded to 3 significant digits is 2.34

-    If your answer ends with 5, increase the preceding number by 1 if it is odd, leave the preceding   

     number unchanged if it is even.

     18.35 rounded to 3 significant digits is 18.4

     18.25 rounded to 3 significant digits is 18.2


Exercises:

1.    Determine the number of significant digits in the following measurements.
a)    32.07 m
b)    0.0047 g
c)    5 x 105 kg
d)    6400 s
e)    204.0 cm
f)      0.000 001 µm
g)    0.156 345 g
h)    10.0 cm

 2.    Express each answer using the correct number of significant digits.
a)    55.671g + 45.78
b)    1.9 mm + 0.62 mm
c)    87.9478 L – 86.25L
d)    0.350 mL + 1.70 mL + 1.019 mL
e)    5.841 g x 6.03 g
f)      17.51g ÷ 2.2 cm3
g)    23 457.12 cm x 45.341 cm